In a small bowl, whisk the pumpkin pie spice, cayenne pepper, salt, and powered sugar together. Set aside.
Melt the butter in a large skillet over medium heat. Add the pecans and stir to coat in the butter. Cook, stirring constantly, until fragrant and darkened in color - 3 to 5 minutes. Remove the pan from the heat and sprinkle the spice mixture over the pecans. Stir to coat. Spread the pecans out on a rimmed baking sheet to cool.
* If nutritional values are provided, they are an estimate and will vary depending on the brands used. The values do not include optional ingredients or when ingredients are added to taste.
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